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Synthesis of Two Novel Rhenium(I) Bi

時間:2023-04-29 09:51:41 數(shù)理化學論文 我要投稿
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Synthesis of Two Novel Rhenium(I) Bipyridyl Photosensitive Dyes

Two novel rhenium(I) 2, 2'-bipyridyl complexes, [(4,4'-di-COOEt-bipy) Re(CO)3 (NCCH3)PF6] and [(4,4'-di-COOEt-bipy) Re (CO)3 (NCS)], a model complex [(4,4'-di- COOEt- bipy) Re (CO)3 (pyridine)PF6], were synthesized.Their ground state electronic spectra and emission spectra were measured in acetonitrile.The MLCT absorption maximum of the complex exhibited a considerable red shift as the ligand changed from pyridine to CNCH3, or SCN.

作 者: Shi Guo SUN Xiao Jun PENG Ming Wen FAN Yong Qian XU Lei Shi Li Cheng SUN   作者單位: State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012  刊 名: 中國化學快報(英文版)  ISTIC SCI 英文刊名: CHINESE CHEMICAL LETTERS  年,卷(期): 2004 15(8)  分類號:   關鍵詞: Rhenium(I) 2,2'-bipyridyl complex,photosensitizer,red shift  

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